QLE-ESH

成分	CAS No	化学式	浓度占比
硫酸 Sulfuric acid	7664-93-9	H2SO4	0.50%
硫酸銅(II)五水合物 Copper sulfate pentahydrate	7758-99-8	CuSO4·5H2O	0.50%
有機化合物 Organic compound	商业机密	商業秘密	0.50%
水 Water	7732-18-5	H2O	98.50%

名称	联系电话	邮编	地址	传真号码	电子邮件
MITSUBISHI MATERIALS CORPORATION Sanda Plant	81-79-568-2306		12-6 Techno Park, Sanda-shi, Hyogo, Japan

#	料号	使用部门	属性	危险化学品
尚无任何资料

#1: 化學品與廠商資料

化學品名稱 (Product Name) ：MULAS W27-A2

其他名稱 (Other Names) ：-

建議用途及限制使用：電鍍製程中的添加劑

Recommended use and restrictions on use ：Additive for plating process

製造者名稱,地址及電話 (Names, addresses, and phone numbers of the manufacturer)：

製造者(Manufacturer) ：MITSUBISHI MATERIALS CORPORATION Sanda Plant

地址(Addresses) ：12-6 Techno Park, Sanda-shi, Hyogo, Japan 669-1339

電話(Phone numbers) ：81-79-568-2306

輸入者名稱,地址及電話 (Names, addresses, and phone numbers of the importer)：

輸入者(Importer) ：揚博科技股份有限公司 Ampoc Far East Co. Ltd.

地址(Addresses) ：桃園市中壢區中壢工業區定安路五號

電話(Phone numbers) ：03-4617200

緊急聯絡電話 (Emergency contact phone numbers)：

81-79-568-2300 (日本 Japan) ， 03-4617200 (台灣 Taiwan)

#2: 危害辨識資料

化學品危害分類：

金屬腐蝕物第 1 級，腐蝕 / 刺激皮膚物質第 1 級，嚴重損傷 / 刺激眼睛物質第 1 級。

Product hazard class :

Corrosive to metals :Category1, Skin corrosion / irritation :Category1, Serious eye damage /

irritation :Category1

標示內容 (Label content)：

圖式符號：腐蝕

Symbol ：Corrosion

警示語：危險

Signal words ：Danger

危害警告訊息：

可能腐蝕金屬

造成嚴重皮膚灼傷和眼晴損傷

造成嚴重眼晴損傷

Hazard Statement：

May be corrosive to metals

Causes severe skin burns and eye damage

Causes severe eye damage

危害防範措：

請依規定使用

於通風處存取藥水

於取用藥水時穿著用防護衣物

避免接觸到眼睛，皮膚及衣服

若不慎翻倒藥水立即以水沖洗

處置藥水後徹底清洗手及漱口

鎖緊存放

洗滌後處置容器

Precautionary statement：

Do not use except an original usage.

Handle chemical at the ventilating place.

Wear suitable protective clothing at handling operation.

Avoid contact with eyes, skin and clothing.

In case that chemical is spilled, wipe off immediately.

Wash the hands and gargle after handling operation.

Keep containers tightly closed at all time.

Dispose the container after washing.

其他危害 (Other hazards)：-

#3: 成分辨識資料

混合物 (Mixtures)：

中英文名稱 Chinese and English names	同義名稱 Synonyms	化學式 Chemical Structure	化學文摘社登記號碼 CAS No.	濃度(成分百分比) Concentration (Ingredient percentage)
硫酸 Sulfuric acid	-	H2SO4	7664-93-9	0.5%
硫酸銅(II)五水合物 Copper sulfate pentahydrate	-	CuSO4･5H2O 7	7758-99-8	0.5%
有機化合物 Organic compound	-	商業秘密 Trade secret	商業秘密 Trade secret	0.5%
水 Water	-	H2O	7732-18-5	98.5%

#4: 急救措施

不同暴露途徑之急救方法：

吸入：移到新鮮空氣處，如呼吸微弱給予人工呼吸。靜置患者給予毛毯。如有不舒服立

即求醫/ 送醫。

皮膚接觸：脫掉沾染的衣服。用大量肥皂和水清洗。如有不舒服立即求醫/ 送醫。

眼睛接觸：以水持續清洗眼睛 15 分鐘。保持眼睛張開。如有不舒服立即求醫/ 送醫。若太晚

清洗眼睛或清洗不適當可能導致眼睛不適。

食入：立即以水清洗口腔內部。不得誘導嘔吐。如有不舒服立即求醫/ 送醫。若患者已

失去意識不得由口給予任何物品

The first aid measures for different exposure routes：

Inhalation ：Remove the victim to fresh air. Do artificial respiration in case of weak breath. Hold

the quiet keeping the victim with blanket. Immediate medical attention is required.

Skin contact ：Remove contaminated clothing and wash with soap and water. Immediate medical

attention is required.

Eye contact ：Flush the eye with water for at least 15 minutes, while holding the eye open.

Immediate medical attention is required. If flushing is late or is inadequacy, it might

cause to disorder of eyes.

Ingestion ：Wash the inside of mouth with water. Do not induce vomiting forcibly. Immediate

medical attention is required. Never administer anything by mouth if a victim is

最重要症狀及危害效應：-

The most important symptoms and hazardous effects : -

對急救人員之防護：-

The protection of first-aiders ：-

對醫師之提示：-

Notes to physicians ：-

#5: 滅火措施

適用滅火劑：霧狀水，泡沬，乾粉，二氧化碳

Suitable fire extinguishing media：Water spray, Foam, Powder, Carbon dioxide

滅火時可能遭遇之特殊危害：燃燒時，會生成對人體健康有害的氣體

Specific hazards may be encountered during fire-fighting : During fire, gases hazardous to health

may be formed.

特殊滅火程序：將燃料遠離火源並使用減火器。

Specific fire-fighting methods ： Cut the fuel to fire resource and use fire extinguisher.

消防人員之特殊防護裝備：防火衣物，護目鏡，空氣呼吸器及手套。

Special equipment for the protection of firefighters : Heat-resistant clothes, Goggle, Gas mask,

Glove, etc

#6: 洩漏處理方法

個人應注意事項：撤離人員至下風處。嚴禁人員進入該洩露區。如在室內，對該區域進行通

風。於上風處工作時穿著防護設備。

Personal precautions ：Evacuate the person in leeward. Prohibit to entry of people to the place where

chemical is leaking. Ventilate the area sufficiently until disposal ends in case of indoor. Work from

windward wearing protective equipment regularly.

環境注意事項：勿直接排放至水源處。

Environmental precautions ：Do not discharge directly to a water

清理方法：若微量洩露時，在汲取洩露的藥水至空容器後進行該區的清洗。若大量洩露時，先中

斷流出並將藥水放至安全處，洩露藥水立即汲取至空容器。並以氫氧化鈣，蘇打粉再加大量的

水進行清洗。

Methods for cleaning up : In case of a little leaking, flush out after taking leaked substance into

another empty container. In case of large leaking, stop its flow and lead to safety area firstly, and

take the leaked substance as completely as possible into another empty container. The remains are

neutralized with calcium hydroxide, soda ash or flushed with much water.

#7: 安全處置與儲存方法

處置：

使用在通風良好的地方(設置局部排氣裝置等)

需備有清洗眼睛及淋浴的設備

每次使用後確保容器之開闔

穿著防護衣物以防處置藥水時濺到眼睛，皮膚及衣服

於接觸過容器後清洗手部及臉部

使用本產品時不要進食，飲水或吸煙

勿粗暴丟下拍打及拖拉容器

Handling：

Use at the ventilating place. (Set up the partial exhaust device etc..)

Facilities should be equipped with an eyewash facility and a safety shower.

Open and close the container in each use.

Wear suitable protective clothing at handling operation to avoid contact with eyes, skin and clothing.

Wash the hands and face after handling operation.

Do not eat, drink or smoke when using this product.

Do not treat roughly to throw down, drop, inflict impulse, and drag the container.

儲存：

因為強酸，避免金屬和鹼接觸

置於乾燥，通風良好處，避免陽光直射

儲存密閉的容器前先擦拭容器瓶身

貯存容器於可上鎖的空間以防被竊或不見

避免長時間之儲存

Storage：

Avoid contacting with metal and alkali because of strong acid.

Storage area should be dry, well ventilated, out of direct sunlight.

Store the sealing container after wiping an outlet in each use.

Store the container for the locked area not to be stolen and lose.

Avoid the long-term storage.

#8: 暴露預防措施

工程控制： 1. 建置部分排氣系統或可緊密抑制水氣。 2. 建置淋浴及沖洗間於使用藥水區域的附近，並清楚指出其位置。 Engineering control: 1. Set up the partial exhaust system or cover the vapor source tightly. 2. Set up a shower and washroom near the handling operation place, and indicate the place plainly.
控制參數 (Control parameters):
八小時日時量平均容許濃度 Time weighted average exposure limits (8hours) TWA	短時間時量平均容許濃度 Short-term exposure limits STEL	最高容許濃度 Maximum exposure limits CEILING	生物指標 Biological standards BEIs
1mg/m3 (硫酸) 0.2mg/m3 (以銅計)	2mg/m3 (硫酸) 0.6mg/m3 (以銅計)	-	-
1mg/m3 (Sulfuric Acid) 0.2mg/m3 (As Copper)	2mg/m3 (Sulfuric Acid) 0.6mg/m3 (As Copper)	-	-
個人防護設備： 1. 呼吸防護：口罩 2. 手部防護：耐酸鹼手套 3. 眼睛防護：護目鏡 4. 皮膚及身體防護：塑膠圍裙，塑膠鞋 Personal protective equipment: 1. Respiratory protection : Mask 2. Hand protection : Acid alkali resistant glove 3. Eye protection : Goggle 4. Skin and body protection : Rubber apron, Rubber boot
衛生措施：處置後清洗手。 Hygiene measures ：Wash the hands after handling.

#9: 物理及化學性質

外觀：青色液體 Appearance ：Blue liquid	氣味：無臭 Odor ：Odorless
嗅覺閥值：- Odor threshold ：-	熔點：- Melting point ：
pH 值：低於 2.0 pH value ：Less than 2.0	沸點/沸點範圍：- Boiling point/boiling point range ：-
易燃性(固體，氣體) ：- Flammability (solid, gas) ：-	閃火點：無測試方法(開杯或閉杯) ：- Flash point:( °F °C) ：None Test method: Open cup/ Closed cup ：-
分解溫度：- Decomposition temperature ：-
自燃溫度：‐ Auto-ignition temperature ：‐	爆炸界限：高界限‐ 低界限‐ Explosion limits ：Upper Limit ‐ Lower Limit
蒸氣壓：- Vapor pressure ：-	蒸氣密度(空氣=1) ：- Vapor density ：
密度(水=1) ：1.01 @ 20°C Density ：1.01 @ 20°C	溶解度：可溶於水 Solubility ：Dissolvable to water
辛醇/水分配係數(log Kow) ：- Partition oefficient (n-octanol/water,log Kow) ：-	揮發速率：- Evaporation rate ：-

#10: 安定性及反應性

安定性：正常狀況下安定

Stability ：Stable in the normal conditions

特殊狀況下可能之危害反應：接觸後會金屬腐蝕。與鹼作用會變熱。與氧化劑碰到會突然產生

火或爆炸

Possible hazardous reactions under specific conditions ：Metal corrosion with contact.

Incalescent by reacting with alkali. Fire and explosion by reacting violently with oxidizer.

應避免之狀況：過熱。與應避免的物質接觸

Conditions to avoid ：Excessive heating, Contact with incompatible materials

應避免之物質：金屬，鹼，氧化劑

Materials to avoid ：Metal, Alkali, Oxidizer

危害分解物：一氧化碳，二氧化碳，硫氧化物

Hazardous decomposition products ：Carbon monoxide, Carbon dioxide, Sulfur oxides

#11: 毒性資料

暴露途徑：皮膚，眼睛，吸入，食入

Routes of exposure ：Skin contact, Eye contact, Inhalation, , Ingestion

症狀：

硫酸銅：上呼吸道刺激，胸悶，呼吸困難，味覺有金屬感，胃腸不適，紅斑，皮膚炎，噁

心，腹痛，嘔吐，昏睡，麻痺，結膜炎，角膜潰瘍，混濁，眼瞼水腫

硫酸：咳嗽，呼吸困難，噁心，嘔吐，牙歯糜爛及變色

Symptoms：

Copper sulfate ：Upper respiratory tract irritation, Chest tightness, Short of breath,

Metallic taste sensation, Gastrointestinal discomfort, Erythema, Skin inflammation, Nausea,

Abdominal pain, Vomiting, Drowsiness, Paralysis, Conjunctivitis, Corneal ulcers, opacity,

Eyelid edema

Sulfuric acid ：Cough, Difficulty breathing, Nausea, Vomiting, Dental erosion and discolo

ration of teeth

急毒性：

皮膚

硫酸銅：直接接觸銅鹽可能會造成刺激，紅斑和皮膚炎。

硫酸：稀硫酸可能造成輕度至中度的刺激。

眼睛

硫酸銅：有些銅鹽會造成結膜炎，角膜潰瘍，混濁，以及眼瞼水腫。

硫酸：稀硫酸可引起暫時性傷害，且可能失明。霧滴也會引起刺激性。

吸入

硫酸銅：吸入銅鹽的霧滴可能會造成上呼吸道刺激或是和感冒一樣的不適感，如頭暈和身

體發令。可能會發生胸悶，呼吸困難，味覺有金屬感和胃腸不適等。

硫酸：其蒸氣及霧滴具腐蝕性嚴重的刺激或損害鼻，口，咽及肺，傷害程度依粒子大，

小停留在身體的部位及濃度而異。

食入

硫酸銅：會立即產生一種金屬味覺，大量口水分泌，引起噁心，上腹部灼傷，嘔吐物可能

為青綠色，出現血便，和胃腸出血。

硫酸：硫酸嚴重灼傷口，食道及胃，並會造成噁心，嘔吐，呑嚥困難，喉乾，腹瀉。

Acute toxicity：

Skin

Copper sulfate ：If direct contact with the copper may cause irritation, redness and skin

inflammation.

Sulfuric acid ：May cause mild to moderate irritation.

Eye contact

Copper sulfate ：May causes irritation, erythema and dermatitis for direct contact with the

copper. May cause itching symptoms of erythema.

Sulfuric acid：May cause temporary damage, and possible blindness. Fog drip may also

cause irritation.

Inhalation

Copper sulfate ：May cause tract irritation of upper respiratory, discomfort such as dizziness,

body chills like cold. May occur tightness of the chest, breathing difficulty, discomfort of

metal taste and gastrointestinal.

Sulfuric acid ：Vapor and fog drip may cause severe irritation or corrosive damage to the

nose, mouth, pharynx and lung and depending on degree of injury particles large and small

remain at the location and concentration to the body to another.

Ingestion

Copper sulfate ：It will immediately produce a metallic taste, a lot of saliva secretion, and may

cause nausea, abdominal burns, green vomit, bloody stool, and gastrointestinal bleeding.

Sulfuric acid ：May cause burns of mouth, esophagus and stomach, and cause nausea,

vomiting, result in dysphagia, dry throat and diarrhea.

無分類因為資料不足(吞食 LD50 -)

無分類因為資料不足(皮膚 LD50 -)

Unclassified by data deficiency (Oral LD50 -)

Unclassified by data deficiency (Dermal LD50 -)

慢毒性或長期毒性

硫酸銅：重複或長期接銅鹽可能會造成上呼吸道刺激，鼻炎，打噴嚏，咳嗽，發燒，金屬味覺，

和消化系統功能失常。長期或重複接觸銅可能出現皮膚炎和結膜炎。

硫酸：可使皮膚紅，癢及乾燥。長期暴露於其蒸氣及霧滴會造成牙歯糜爛及變色。

Chronic toxicity or long term toxicity

Copper sulfate ：Repeated or prolonged contact may cause tract irritation of upper respiratory,

rhinitis, sneezing, coughing, fever, metallic taste sensation and digestive system disorders. Long

term or repeated exposure to copper may cause dermatitis and conjunctivitis.

Sulfuric acid ：The skin may become red, itchy and dry. Long-term exposure to its vapors and fog

drops can cause erosion and discoloration of teeth

#12: 生態資料

生態毒性 (Ecotoxicity)：

LC50(魚類)：

硫酸銅：

Copper sulfate ：0.66-1.15mg/L/96h(Lepomis macrochirus)[semi-static] ; 0.96-1.8mg/L/96h

(Lepomis macrochirus) [static] ; 0.1478-0.165 mg/L/96h (Oncorhynchus mykiss) [flow

through] ; 0.09-0.19 mg/L/96h (Oncorhynchus mykiss) [static] ; 0.6752mg L/96h (Pimephales

promelas) [static]

EC50(水生無脊椎動物)：

硫酸銅：

Copper sulfate ：0.147-0.227 mg/L/48h (Daphnia magna) [static]

生物濃縮係數 (BCF)：-

持久性及降解性 (Persistence and degradability)：

半衰期(空氣) ：-

半衰期(水表面) ：-

半衰期(地下水) ：-

半衰期(土壤) ：-

生物蓄積性 (Bioaccumulative potential)：

硫酸：因硫酸在體內易被排泄出、故不具蓄積性。

Sulfuric acid ：Eliminated easily from the body

土壤中之流動性 (Mobility in soil)：

硫酸：因硫酸溶於水、所以當酸溶溢出時、土壤中之水含量及下雨均可影響溢出硫酸之流鮒

佈。一經稀釋後其黏稠度減少、所以在土壤中之流動速度加快。

Sulfuric acid ：Because sulfuric acid is dissolved in water, so when the acid-soluble overflow, the

water content of the soil and sulfuric acid rain may affect the overflow ilk carp cloth. Eliminated

easily from the body. After a diluted reducing its viscosity, so the flow speed of the soil.

其他不良效應 (Other adverse effects) ：-

#13: 廢棄處置方法

廢棄處置方法：

含本産品的排水，先進行活性汚泥等処理。

輕微漏出時，以矽藻土壤吸收漏液後，在規定的地方進行燃燒。

原裝桶子進行丟棄時，先以大量的水進行沖洗。

委託工業廢棄物商處理廢棄物時，提出足夠的產品訊息給廠商。

不要直接將藥水廢棄於水源。

Methods of waste disposal:

Discharge the wastewater including this product after performing processing activated sludge etc.

In case of a little leaking, incinerate in the permitted place after absorbing the substance by the

diatom soil.

Rinse original container with large excess of water before disposing.

In case of consigning to the industrial waste disposal trader, submit the information about this

product sufficiently.

Do not discharge directly to a water source.

#14: 運送資料

聯合國編號 (UN No) ：1760

聯合國運輸名稱：腐蝕性液體，N.O.S (含硫酸)

UN Proper shipping name ：Corrosive Liquid, N.O.S. (Including Sulphuric Acid)

運輸危害分類 (Transport hazard class) ：8

包裝類別 (Packing group) ：III

海洋汙染物：否

Marine pollutant ：Not applicable

特殊運送方法及注意事項：

裝載桶子時注意不要使掉落或破損。裝載桶子時瓶口朝上。不要使桶子曝露在風吹日曬雨淋的環

境。

Specific transport measures and precautionary conditions:

Load the containers not to fall and break. Load the containers upturning the outlet. Do not weather

the container with sunlight and rainwater

#15: 法規資料

適用法規：遵循當地的法規

Applicable regulations ：Follow in accordance with all local, state, and federal regulation.

#16: 其他資料

參考文獻 Literature references	1) JCW Chemical Products Handbook, The Chemical Daily Co., Ltd. (2016) 2) CHEMINDEX, The Chemical Daily Co., Ltd. (2015) 3) 加除式危險物船舶運送及貯蔵規則並関係告示, 成山堂 4) 航空危険物規則書IATA Dangerous goods Regulations, The Japan Air Cargo Institute for Safety (2015) 5) National institute of Technology and Evaluation, HP 6) Japan industrial safety and health association, Japan advanced information center of safety and health, HP 7) ezCRIC, Japan Chemical Database Ltd. 8) Loli (List of Lists) ChemADVISOR Inc
製表者單位 Organization that prepared the SDS	名稱 (Name)：Mitsubishi Materials Corporation Sanda Plant
	地址／電話 (Address/telephone number)： Address: 12-6 Techno-park, Sanda-shi, Hyogo 669-1339 Japan Tel: +81-79-568-2314
製表人 Person who prepared the SDS	職稱 (Title)： Assistant Manager, Production Dept.	姓名(簽章) (Name (signature))： Hironori Uno
製表日期 Date that the SDS was prepared	Sep 4, 2020
備註 Remarks column	上述資料中符號”- ”代表目前査無相關。 ”- ”: No data available.

*注意事項：

 請勿使用於其他目的

 此資料已根據我們所知的提供; 但我們不保證此資料之正確性及安性性

 因為其他未知的危害，請謹慎的使用此物品

 根據此資料及貴公司之風險，小心謹慎的決定安全的使用方式

 本公司之安全資料表將會依新的知識及檢查日期做更新

*NOTICE

・Do not use except an original use.

・The information contained herein is drawn based on the best of our date.

However, we cannot warrant the accuracy and safety of this information.

・Scrupulous care is necessary for handling operation because of unknown harmful in chemical products.

・Decide the way of safety handling operation at your own risk referring this information.

・Our company’s SDS is revised by new knowledge and examination date without warning.

MULAS W27-A2

基本资料

供应商

化学品