化学品名称：Phichem Lead-free Solder ball Series 无铅锡球其他名称：不适用产品系列：Sn98.25Ag1.2Cu0.5Ni0.05球径：可依客户要求建议用途：电子与半导体元件、焊接合金限制使用：仅限工业焊接使用

制造商 / 供应商名称：上海飞凯材料科技股份有限公司地址：上海市宝山区潘泾路 2999 号，201908电话：86-21-50551001邮箱：tech@phichem.com.cn

紧急联络信息紧急电话：86-21-50551001传真：86-21-58993079生效日期：2024/07/19有效期限：3 年

Emergency overview 紧急情况概述: May cause damage to organs through prlonged or repeated exposure.长时间或反复接触可能造成器官损害。

Items Hazard Classification 化学品危害分类: Specific target organ toxicity (repeated exposure) ( Hazard category 2)特异性靶器官毒性反复接触类别2

Pictogram (s) 象形图 Hazard Classification 危险类型 Health Hazards.健康危害。 Signal Word 信号词 Warning.警告。 Hazard Statement 危险说明 May cause damage to organs through prolonged or repeated exposure. 长时间或反复接触可能造成器官损害。 Precautionary Statement 防范说明 Response: Get medical advice/attention if you feel unwell. Prevention : Do not breathe dust/fume/gas/mist/vapours/spray. 预方措施:不要吸入粉尘/烟/气体/烟雾/蒸气/喷雾。

|  | 应对措施:如觉不适,求医/就诊。 Storage: Store in a well-wentilated place. 存放:存放在通风良好的地方。 Disposal: Dispose of container in accordance with local/regional/international regulations. 处置:按照当地法规相关规定处置内装物和容器。 | | --- | --- | | Taint Path 暴露途径 | Inhalation、 Skin Contact、 Eye Contact、 Ingestion。 吸入、皮肤接触、眼睛接触、食入。 | | Environmental Hazards 环境危害 | Not applicable.不适用。 | | Explosion Risk 燃爆危险 | Not applicable.不适用。 | | Other Hazard其他危害:No relevant document.无相关资料可查。 | |

First Aid Methods for Different Exposure Pathways不同暴露途径之急救方法: Inhalation Remove to fresh air. If not breathing, have a trained individual administer oxygen. Get 吸入 medical attention immediately. Skin Contact 皮肤接触 将患者移至清新空气处,如果患者已停止呼吸,则施以人工呼吸并送急诊。 用适合的肥皂和清水清洗皮肤。除去污染的衣服。如果皮肤发炎,马上就。 Wash contaminated skin with non-abrasive soap and running water. Remove contaminated clothing. Get medical attention if skin iritation. 眼睛接触 Eye Contract least 15 minutes and get medical attention. Check for and remove any contact lenses, immediately flush with plenty of water for at

Ingestion
检查并移除任何隐形眼镜，马上用大清水冲洗至少15分钟，立即就医。Gargle. Induce vomiting by the medical staff instructions.
食入
漱口。由医疗人员指示催吐。
TheMost Important Symptoms and HazardousEffect最重要症状及危害效应：Irritation and excessive exposure to hot steam cause pulmonary edema.刺激感及过量吸入热蒸气会造成肺水肿。
Protection forFirst-aid Personnel对急救人员之防护：
Wear gas masks, oxygen cylinders and protective clothing for First-aid personnel.急救人员应配戴防毒面罩或氧气筒及防护衣。
Prompt toDoctor对医师之提示：
Silver and inorganic compounds are neurotoxicants, they maybe bring peripheral nervous diseases.银及其无机化合物为神经毒物，可能引起末梢神经疾病。

Suitable Extinguishing
适用灭火剂
Carbon dioxide, extinguishing powder or water spray.
二氧化碳灭火剂，干粉或者水。
Special dangerous that may
encounter while fire fighting
灭火时可能遭遇之特殊危害
No relevant document.
无相关资料可查。
Special fi re fighting procedure
特殊灭火程序
Not suitable.
不适用。
Special safety equipment fire
消防人员之特殊防护设备
No relevant document.
无相关资料可查。
Hazardous properties
危险特性
Not suitable.
不适用。
Hazardous combustion
products
Not suitable.
有害燃烧产物
不适用。

Personal precautions
个人应注意事项
Avoid inhalant soldering exhaust gas or dust.
避免吸入锡烟气或粉尘。
Environmental precautions
环境注意事项
Don't spread over the area.
勿使泄露区域广大。
Clean-up methods
清理方法
Pump the air or water spray.
抽气或冲洗。

Handling
处置
Keep 20 cm when soldering. The fumes produced during soldering should be extracted away from the breathing zone of the operators, use in a well ventilated area. When using, avoid contact or breathing. Do not eat, drink or smoke.

Thoroughly wash hands with soap and water after handling. Good industrial hygiene practices
should be followed.
焊接时，保持20厘米距离。在焊接期间产生的烟雾应该被抽离操作者的呼吸区域，应在
一个通风的地区里操作焊接。当焊接时，避免接触或者吸入。工作场所禁止吃东西，喝
饮料及抽烟。操作后彻底洗净，保持良好工业卫生惯例。
Storage
储存
The guarantee of shelf life for solder ball is 1 year (12 months) when solder balls are stored
under unopened bottles and pointed storage condition as following.
当锡球存放于未拆封的瓶子与以下的储藏环境时，锡球货架寿命的保证为一年(12个月）。
Temperature/温度:25+/-10℃
Humidity/湿度:<65%RH

Engineering Control工程控制: Provide adequate mechanical exhaust.提供足够的机械式排气装置。 Monitoring method监控方法: Not applicable.不适用。 Control Parameters控制参数: Allowable Concentration 容许浓度 Elemen 元素 Ag Sn t 8小时平均容 0.1 mg/m3 2.0 mg/m3 许浓度 TWA TLVo 短时间时平均 0.03 mg/m 4.0 mg/m3 容许浓度 STEL PELo 最高容许浓度 Ceiling --- Other Ni 0.1 mg/m3 0.3 mg/m3 Cu 0.02mg/m3 --- --- Biological Indicators 生物指标 Not applicable.不适用。 Personal Protection Equipment个人防护设备: Hands手部 Respiratory呼吸 Suitable gloves防护手套。 Wear a protective mask as needed. 根据需要,佩戴防护面具。 For handling: wear safety glasses with side shields. For melting, wear goggles Eyes眼 and face shields. Don't wear contact lenses. 操作时:配戴安全眼镜。熔化化合物时,配戴护目镜和面罩。不要戴隐形 眼镜。 Skin and Body 皮肤及身体 Wear coveralls and protective gloves. Inspect gloves before using. 应穿戴工作衣及防护手套。在使用之前,检查手套。 Ambulance staff protection Wear gas masks, oxygen cylinders and protective clothing. Other precautions 救护人员防护 配戴防毒面罩或氧气筒及防护衣。 Forbid eating, drinking, smoking and make up in the workplace.

其他注意事项
工作场所禁止吃东西，喝饮料、抽烟及化妆。
Hygiene practices卫生措施：
Thoroughly wash exposed areas with soap and water before leaving work, eating, drinking and smoking.
工作后，吃东西、喝饮料或抽烟前应洗手。

| Olfactory Threshold 嗅觉阈值: Not applicable 不适用 |  | | --- | --- | | pH 值: Not applicable 不适用 | Flash Point 闪火点: Not applicable 不适用 | | Flammability 易燃性(固体、气体): | Not applicable 不适用 | | Not applicable 不适用 | Heat of Combustion 燃烧热 $(kJ / mol)$ : Not applicable 不适用 | |  | Explosion Limit爆炸界限: | | Vapor Pressure 蒸气压: Not applicable 不适用 |  | |  | Ignition Temperature 引燃温度: Not applicable 不适用 | | Solubility 溶解度: Insoluble in water 不溶于水 | Evaporation Rate 挥发速率:Not applicable 不适用 | | 辛醇/水分配系数:Not applicable 不适用 |  |

Special circumstances of the hazard Reaction特殊情况下可能之危害反应: Not applicable.不适用。 Materials to Avoid应避免之物质: Chemical Stability 安定性: Stable under room temperature and pressure.正常状况下安定。 Conditions to Avoid 应避免之状况:Contamination. Contact with air or water.与空气或者水接触。 Avoid oxidizing agents, acids, peroxides, moisture, chlorine, alkalies. 避免具氧化性之物质,酸,过氧化物,水分,氯,及。 Hazardous decomposition products 危害分解物: Not applicable.不适用。 Belongings against 禁配物: Not applicable.不适用。

Acute Toxicity
LDs/经口
LDso/经皮24h
LDs0/吸入
其它
急毒性
NA
NA
NA
NA
Symptoms症状：
Coughing，difficulty breathing，headache,nausea，vomiting.咳嗽、呼吸困难、头痛、恶心、呕吐。
Chronic Toxicity or Long-term Toxicity慢毒性或长期毒性：Norelevant document.无相关资料可查。
Induced sensitivity 致敏感性：NA
Irritation刺激性：NA
Induced mutation致突变性：NA
Teratogenicity 致畸性：NA
Reproductivc toxicity生殖毒性：NA
Specific targetorgan systemic toxicity特异性靶器官系统毒性：Norelevant document.无相关资料可查。
Other其它：NA

Eco-toxicity 生态毒性: LC50(Fish鱼类):NA EC50(Aquatic invertebrates 水生无脊椎动物):NA biological Concentration factor 生物浓缩系数(BCF): NA Bioaccumulation 生物蓄积性: NA Persistence and Degradability 持久性及降解性:NA Biodegradable 生物降解性:NA Non-biodegradable 非生物降解性:NA The Mobility in soil上壤中之流动性:NA Other Adverse Effects其他不良效应:NA

Disposal Considerations 废弃处置方法:

To comply with relevant goverment laws and regulations dealing with.遵行政府相关法规处理。

UN.No联合国编号：NA
The United Nations shipping name 联合国运输名称：NATransportation hazard classification运输危害分类：NAPacking包装类别：NA
Marine pollutant 海洋污染物(是/否)：NA
Special Shippingand Notes特殊运送方法及注意事项：NA

Applicable Laws and Regulations适用法规：
1.Occupational safetyand sanitation rules.职业业安全卫生设施规则
2.Hazards and hazardous materials rules of Liberal Studies.危险物及有害物通规则。
3. Labor working industry in ambient air concentrations of hazardous materials to allow the standard.工作业环境空气中有害物容许浓标准。
4.Road Traffic Safety Rules.道交通安全规则。
5. Industrial Waste Management Methods for storage clearance office and Facilities Standards.事业废弃物贮存清除处方法及设施标准。
List of ChemicalsManagement inChina中国化学品管理名录：
1. Catalogue of Hazardous Chemicals (2015)
危险化学品目录（2015年版）
未列入
2.
. Catalogue of Key Environmental Management Dangerous Chemicals重点环境管理危险化学品目录
未列入
3.China's Strict Listof Toxic Chemicals中国严格限制的有毒化学品名录
未列入
4. Catalogue of Narcotic Drugs and Psychotropic Substances (2013)
未列入
麻醉药品和精神药品品种目录（2013版）
5. List of Hazardous Chemicals under Special Supervision (batches I and 2)重点监管的危险化学品名录（第1和第2批）
未列入
6. List of Controlled Ozone Layer Depleting Substances in China's Imports and Exports （batches 未列入1to6）中国进出口受控消耗臭氧层物质名录（第1到6批）
7. List of Inflammable and Explosive Dangerous Chemicals (2017)制爆危险化学品名录（2017年版）
未列入
8.List of High Toxic高毒物品目录
镍列入
其余未列
入

I.AIR PRODUCTS MSDS、 INTERN TIONAL MARITIME DANGEROUS GOODS 2.MSDS Library, CCINFO, 9 9 -2, 2006-1 CODE References 参考文献 3.RTECS Library, TOMES PLUS, Vol.68, 2006 7.GB30000,化学品分类和标签规范 4.HSDS Library, TOMES PLUS, Vol.68, 2006 5.GB/T16483-2008,化学品安全技术说明书内容和项目顺序 6.GB/T17519-2013,化学品安全技术说明书编写指南

制表者单位 Tabulated Company Name 名称:PhiChem Corporation.上海飞凯材料科技股份有限公司 Address 地址: 2999 Panjing Road, Baoshan, Shanghai, China, 201908 上海宝山区潘泾路2999号邮编:201908 Telephone电话:86-21-50551001 Fax传真:86-21-58993079 Prepared by 制表者 Position职称:PSRA Engineer Name (Signature)姓名(签章):Wang Linjing 制表日期 Tabulated Date 2024/07/19 Rev./Edit Description 2024/07/19 A1 新版发行。 版次/修改说明 其他信息 Other message NA The data contained herein are furnished for information only and are believed to be reliable. However, Shanghai PhiChem Material Corporation Limited ("PhiChem*) does not assume responsibility for any results obtained by persons over whose methods PhiChem has no control. It is the user's responsibility to determine the suitability of PhiChem's product or any production methods mentioned herein for a particular property and persons against any hazards that may be involved in the handling and use purpose, and to adopt such precautions as may be advisable for the protection of Disclaimer of any hazards that may be involved in the handling and use of any PhiChem's 免责声明 purpose, arising from sale or use of PhiChem's products. PhiChem further disclaims products. In light of the foregoing. PhiChem specifically disclaims all warranties. express or implied, including warranties of merchantability and fitness for a particular any liability for consequential or incidental damages of any kind, including lost profits. 本说明书是基于我们现在的知识水平所得,它不是产品特性的保证书。安全技术 说明书的使用者应根据使用目的,对相关信息的合理性做出判断。我们对该产品 操作、存储、使用或处置等环节产生的任何损害,不承担任何责任。