Chemicals names 

化學品名稱 

無鉛焊錫球 (AH68U) 

Lead-Free Solder Sphere (AH68U) 

Other Names 

其他名稱 

- 

Recommended use 

and restrictions on use 

建議用途及限制使用 

半導體工程 

Semiconductor Engineering 

Manufacturer, Importer or Supplier Name 

製造者、輸入者或供應

者名稱 

恆碩科技股份有限公司 

ACCURUS SCIENTIFIC CO., LTD. 

Address 

地址 

台灣 717 台南市仁德區文賢路一段 508~51 號 

No.508-51, Section 1, Wen-Sien Road, Rende District, Tainan City 717, Taiwan 

Telephone 

電話 

06-3661288 

+886-6-3661288 

Fax Number 

傳真 

06-2660474 

+886-6-2660474 

Emergency Telephone 

緊急聯絡電話 

06-3661288 

+886-6-3661288 

Hazard classification of the Chemicals 化學品危害分類：健康危害-特定標的器官系統毒性物質-重複暴露-二級。 

Specific target organ systemic toxicity following repeated exposure. ( Hazard category 2) 

Label content標示內容 

Label Format: Health Hazards 象徵符號：健康危害 

Signal words: Warning 警示語：警告 

Hazard statements:  

危害警告訊息： 

H373: May causes damage to organs through prolonged or repeated exposure. 

H373: 長期或重複暴露會對器官造成傷害。 

Precautionary statements: 

危害防範措施： 

P301+P310: IF SWALLOWED: Immediately call a POISON CENTER/doctor/… 

P301+P310: 若不慎吞食：立即呼救毒物中心/醫師。 

P264: Wash hands thoroughly after handling. 

P264: 處理後徹底洗淨雙手. 

P270: Do not eat, drink or smoke when using this product. 

P270: 使用本產品時，不得飲食、喝水或抽菸。 

P271: Use only outdoors or in a well-ventilated area. 

P271: 只能在戶外或通風良好的地方使用。 

Other hazards其他危害：該產品以合金形式存在。當各個組分為粉末狀時，不會帶來相同的危害。 

This product is present form as an alloy. It does not present the same hazards when the individual components are in their powdered form. 

Chemical property化學性質 

Chinese and English names of The hazardous ingredients 

危害物質成分之中英文名稱 

Concentration or concentration ranges 

(% of contents) 

濃度或濃度範圍(成分百分比) 

CAS no. 

錫/Tin 

95-97 

7440-31-5 

銀/Silver 

2.8-3.2 

7440-22-4 

銅/Copper 

0.3-0.7 

7440-50-8 

鎳/Nickel 

0.03~0.07 

7440-02-0 

The first-aid measures for different exposure routes不同暴露途徑之急救方法 

Inhalation 

吸入 

1. 立即將患者移至新鮮空氣處並依需要維持其呼吸暢通。 

Immediately move the patient to the ventilation and hold his breathing unimpeded. 

1. 若呼吸停止，施予人工呼吸。 

   Offering the artificial respiration if patient stop breathing or dyspnea. 

2. 保持患者溫暖及休息。 

   Keep the patient warm and rest. 

3. 立即就醫。 

   Seek medical advice immediately. 

skin contact 

皮膚接觸 

1. 以大量的清水沖洗。 

   Use considerable water to wash. 

2. 沖掉沾染的化學品再立即用肥皂及水清洗皮膚。 

   The chemicals washed out and use the soap and water wash the skin. 

3. 如仍有刺激感，立即就醫。 

   If still have sense of stimulating, Please seek medical advice immediately. 

eye contact 

眼睛接觸 

1. 勿讓患者搓揉眼睛或緊閉眼睛。 

   Don't let the patient knead or close the eyes. 

2. 小心地撐開眼皮並立即沖洗，連續沖洗至就醫為止。 

   Carefully open the eyelid and use water wash, Continuously wash it to seeking medical advice. 

3. 儘速就醫。 

   Seek medical advice immediately. 

Ingestion 

食入 

1. 勿餵食任何東西及催吐（除非醫療人員指示）。 

   Don’t queasy and feed the food (Unless medical instructions of personnel). 

2. 立即就醫。 

   Seek medical advice immediately. 

The most important symptoms and hazardous effects 最重要症狀及危害效應 

1. 銀中毒、銅中毒及末梢神經疾病。 

 silver poison、copper poison and nerve ending illness. 

1. 刺激感及過量吸入熱蒸氣會造成肺水腫。 

Excitement and excessive inhale hot vapor can cause lung edema. 

The protection of first-aiders 

對急救人員之防護 

應配戴防毒面罩或氧氣筒及防護衣。 

Must wear the gas masks or oxygen mask and protective clothing. 

Notes to physicians 

對醫師之提示 

1. 患者吞食時，考慮洗胃。 

The patient considers gastric lavage when eating. 

1. 銀及其無機化合物為神經毒物，可能引起末梢神經疾病。 

Silver and inorganic compound is the neural poisonous substance, can cause nerve ending disease. 

Fire-fighting measures 

適用滅火劑 

水、泡沫、乾粉及二氧化碳滅火劑。 

Water, Foam, Powder and CO2 extinguisher. 

Suitable fire extinguishing media 

滅火時可能遭遇之特殊危害 

無相關資料可查。 

No relevant information for inquiring. 

Specific hazards may be encountered during fire-fighting 

特殊滅火程序 

不適用。 

Not application. 

Specific fire-fighting methods 

消防人員之特殊防護設備 

氧氣筒及防護衣。 

Oxygen cylinder and protective clothing. 

Personal precautions 

個人應注意事項 

避免吸入銲錫煙氣或粉塵。 

Avoid sucking the solder gas or powder. 

Environmental precautions 

環境注意事項 

勿使洩露區域擴大。 

Don't let the area of leakage be expanded. 

Methods for cleaning up 

清理方法 

冷卻後可進行回收。 

Recoverable after cooling. 

Handling 

處置 

依廢棄物處理法規處理。 

According to the refuse disposal ordinance disposal. 

Storage 

儲存 

1. 儲存於適當的容器內並做標識。 

Store in the appropriate container and do identification. 

1. 置於陰涼、乾燥及通風良好區，避免高溫。 

Put on the shade, drying and ventilate the good place, and avoid the high temperature. 

1. 遠離氧化劑如氯氣、酸與過氧化氫等。 

   Far away the oxidant (ex: chlorine, acid and hydrogen peroxide…). 

2. 貯藏溫度：<50℃ 

Custody Temperature : <50℃ 

Engineering control 工程控制 

Control parameters 控制參數 

Element of The hazardous 

ingredients 

元素中英文名稱 

8 hours time weighted average 

exposure limits 八小時日時量平均容許濃度 

TWA 

Short-term exposure limits 超時間時量 

平均容許濃度 

STEL 

maximum exposure 

limits 

最高容許濃度 

CEILING 

biological standards 生物指標 

BEIs 

錫/Tin 

2 mg/m³ 

4 mg/m³ 

- 

- 

銀/Silver 

0.01 mg/m³ 

0.03 mg/m³ 

- 

- 

銅/Copper 

0.2 mg/m³ 

0.6 mg/m³ 

- 

- 

鎳/Nickel 

1 mg/m³ 

2 mg/m³ 

Personal protective equipment 個人防護設備 

respiratory protection 

呼吸防護 

• 一般使用：配戴口罩。 

General: Wear the gauze mask. 

• 緊急狀況：粉塵或煙霧超過容許濃度時，應配戴防粉塵及煙霧的防毒面具。 

Emergency: Dust or smog exceeds permitting the concentration, need wear avoid dust and smog gas mask. 

hand protection 

手部防護 

橡膠或塑膠的防護手套。 

Rubber or plastic protective gloves. 

eye protection 

眼睛防護 

配戴安全眼鏡及/或面罩(當有粉塵飄散或熱金屬噴濺時)。 

Put on the safe glasses and/or mask (If there is dust fly about or hot metal splashing). 

skin  and  body protection 

皮膚及身體防護 

應穿戴工作衣及防護手套以避免灼燙傷。 

Need wear the smock and protective gloves avoid badly burned. 

Hygiene measures 

衛生措施 

工作後，吃東西、喝飲料或抽煙前應洗手。 

Wash hands before eating, drinking the beverage or smoking. 

Appearance (physical state, color, etc.) 

外觀（物質狀態、顏色等） 

物質狀態：固態 

Physical state: solid 

形    狀：球狀 

Form: sphere 

顏    色：銀灰色 

Color: silver 

Odor 

氣味 

無氣味 

No smell 

Odor threshold 

嗅覺閾值 

- 

Melting point(Solidus Line) 

固態熔點 

217±2℃ 

PH value 

PH 值 

- 

Boiling point/boiling range 

沸點/沸點範圍 

- 

Flammability (solid, gas) 

易燃性（固體、氣體） 

不易燃 

No Flammability. 

Flash point 

閃火點 

- 

^oF 

- 

^oC 

Test method 

測試方法 

□ Open cup 開杯 

□ Close cup 閉杯 

Decomposition temperature 

分解溫度 

- 

Auto ignition temperature 

自燃溫度 

- 

Explosion limits 

爆炸界限 

- 

Vapor pressure 

蒸氣壓 

- 

Vapor density 

蒸氣密度 

- 

Density 

密度 

7.4±0.2 

Solubility 

溶解度 

- 

Partition coefficient(n-octanol/water, 

辛醇／水分配係數（log Kow） 

- 

Evaporation rate 

揮發速率 

- 

Stability 安定性: 正常狀況下安定 

Stable under normal conditions 

Possible hazardous reactions occurring under specific conditions 

特殊狀況下可能之危害反應 

 金屬錫與松節油接觸會產生火災和爆炸。 

This metal tin and turpentine contact will result fire and explode.  

Conditions to avoid 應避免之狀況 

1. 500℃以上高溫作業，會散出具有毒性的錫氧化物。 

Above 500℃ high-temperature work, will produce the contain toxic tin oxides. 

1. 粉末狀態於空氣中會氧化。 

Powder state will be oxidized in the air. 

Materials to avoid 

應避免之物質 

對於氧化劑、酸、濕氣有輕微的反應 

With oxide, acid and humidity there is slight response. 

Hazardous decomposition products 

危害分解物 

- 

Routes of exposure 

暴露途徑 

吸入、皮膚接觸、眼睛接觸、食入 

Inhalation, skin contact, eye contact, ingestion 

Symptoms 

症狀 

肺泡水腫、上呼吸道刺激、咳嗽 

Alveolar edema, upper respiratory tract irritation, cough 

Acute toxicity 

急毒性 

過量吸入熱蒸氣會造成肺水腫。 

Excessive inhalation of hot steam can cause pulmonary edema 

LD50 (測試動物、吸收途徑)：- 

LD50 (tested animal, way of absorption):- 

LC50 (測試動物、吸收途徑)：- 

LC50 (test animal, absorption route):- 

Chronic toxicity or long term toxicity 

慢毒性或長期毒性 

吸入、皮膚接觸、眼睛接觸、食入 

Inhalation, skin contact, eye contact, ingestion 

Ecotoxicity 

生態毒性 

- 

Persistence and degradability 

持久性及降解性 

- 

Bioaccumulative potential 

生物蓄積性 

- 

Mobility in soil 

土壤中之流動性 

- 

Other adverse effects 

其他不良效應 

- 

Methods of waste disposal 

廢棄處置方法 

可回收再利用或依廢棄物處理法處理。 

Utilizing recoverably or according to the refuse disposal ordinance disposal. 

United Nations number(UN No) 

聯合國編號 

- 

UN Proper shipping name 

聯合國運輸名稱 

- 

Transport hazard class(es) 

運輸危害分類 

- 

Packing group 

包裝類別 

- 

Marine pollutant(Yes/No) 

海洋污染物（是／否） 

□ Yes 是   ■ No 否 

Specific transport measures and precautionary conditions 

特殊運送方法及注意事項 

- 

Applicable regulations 

適用法規 

1. 職業安全衛生法 

   Occupational Safety and Health Act 

2. 職業安全衛生設施規則 

   Labor safety and Health Act 

3. 危害性化學品標示及通識規則 

   Regulations for the Labeling and Hazard Communication of Hazardous Chemicals 

4. 勞工作業場所容許暴露標準 

Standards of Permissible Exposure Limits of Airborne Hazardous Substances 

in Workplace 

1. 道路交通安全規則 

   Road traffic safety code. 

2. 事業廢棄物貯存清除處理方法及設施標準 

   Methods and Facilities Standards for the Storage, Clearance and Disposal of Industrial Waste 

References 

參考文獻 

1. 行政院環保署，中文毒理資料庫 

   Environmental Protection Administration, Chinese Toxic Chemicals database. 

2. 勞動部職業安全衛生署，GHS 危害物質資訊查詢系統 

   Occupational Safety and Health Administration, GHS harm material information inquiry system. 

3. 聯合國化學品分類及標示全球調和制度（紫皮書） 

   Globally Harmonized System of Classification and Labelling of Chemicals (GHS) 

4. 關於危險貨物運輸的建議書（橘皮書） 

   UN Recommendations on the Transport of Dangerous Goods 

Data Prepared By 製表 

Company 公司 

恆碩科技股份有限公司 

ACCURUS SCIENTIFIC CO., LTD. 

Address 

地址 

台灣 717 台南市仁德區文賢路一段 508~51 號 

No.508-51, Section 1, Wen-Sien Road, Rende District, Tainan City 717, Taiwan 

Telephone 

電話 

06-3661288 

+886-6-3661288 

Prepared by 

製表人 

吳俊宜 

Mario Wu 

Issued / Review Date 

發布/審查日期 

2023/01/30 

Rev. 

版次 

A1 

Update content 

更新內容 

Review no change 

審核無變化 

Remark 備註 

1. 項目八：TWA & STEL 為純原料之控制參數 

Item 8: TWA & STEL is raw material control parameters. 

1. 上述資料中符號” -“ 代表目前查無相關資料。 

The symbol in materials described above “-" Representative now no relevant information. 

1. 免責聲明 Disclaimer： 

   本文中所含的各種資料僅供參考，並被認為是可靠的。本材料安全數據表的內容僅與銷售的該產品有關，與任何其他材料或在任何過程中使用無關。所有化學產品應僅由具有技術資格的人員使用，或在具有相應技能的人員的指導下使用，這些人員應瞭解所涉及的危險以及在處理過程中進行合理護理的必要性。危害通報法規，美國職業健康與安全（OSHA）和加拿大工作場所有害物質資訊系統（WHMIS）要求必須對員工進行使用物質安全數據表的培訓，以作為危害資訊和響應的來源。 

The data contained herein are furnished for information only and are believed to be reliable. The content of this Material Safety Data Sheet relates only to this product as sold and does not relate to use with any other material or in any process. All chemical products should be used only by, or under, the direction of technically qualified personnel, who are aware of the hazards involved and of the necessity for reasonable care in handling. Hazard communication regulations, United States Occupational Health and Safety (OSHA) and Canadian Workplace Hazardous Materials Information System (WHMIS) require that employees must be trained in the use of Material Safety Data Sheets as a source of hazards information and response.