Chemical description Product name  

Epoxy Molding Compound

SUMIKON® EME-G311Q Type L Ver.CD

SUMITOMO BAKELITE CO.,LTD.

Tennoz Park Side Bldg. 5-8, Higashi-Shinagawa 2-Chome Shinagawa-ku, Tokyo 140-0002, Japan

Phone: +81-3-5462-4038 e-mail: ukqa@sumibe.co.jp

Product uses Recommended use Restrictions on use

Epoxy Molding Compound for Encapsulant of Semiconductors. For Semiconductors.

For industrial use only.

Emergency overview

Hazard categories

Not classified.

*Hazards not stated here are "Not classified", "Not applicable" or "Classification not possible".

Label elements

Pictograms                                    None.

Signal word                                  None.

Hazard statement                       None.

Precautionary statement Prevention

P202                                       Do not handle until all safety precautions have been read and understood

P281                                       Use personal protective equipment as required.

Response

P308 + P313                        IF exposed or concerned: Get medical advice/attention.

Storage

P401                                       Store in accordance with local/regional/national/international regulation.

Disposal

P501                                       Dispose of contents/container in accordance with local/regional/national/international regulations.

Physical and chemical hazards

The product is stable and non-reactive under normal conditions of use, storage and transport. No unusual fire or explosion hazards noted.

Health hazards

Dust may irritate respiratory system. Prolonged inhalation may be harmful. Dust or powder may irritate the skin. Expected to be a low ingestion hazard. Dust may irritate the eyes.

Environmental hazards

The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment.

Other hazards

Not available.

Inhalation         Move to fresh air.

Skin contact           Wash off with soap and water. Get medical attention if irritation develops and persists.

Eye contact           Do not rub eyes. Rinse with water. Get medical attention if irritation develops and persists.

Ingestion          Rinse mouth.  Get medical attention if symptoms occur.

Most important symptoms and health effects

Irritation of eyes and mucous membranes. Dusts may irritate the respiratory tract, skin and eyes.

Expected acute symptoms and delayed symptoms

Not available.

Personal protection for first-aid responders

First aid personnel must wear protective gloves/protective clothing/eye protection/face protection. IF exposed or concerned: Get medical advice/attention.

Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves.

Notes to physician

Treat symptomatically. Symptoms may be delayed.

Extinguishing media        Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).

Extinguishing media to avoid S            Do not use water jet as an extinguisher, as this will spread the fire.

pecific hazards        Development of hazardous combustion gases or vapours possible in the event of fire.

General fire hazards             No unusual fire or explosion hazards noted.

Specific methods           Use standard firefighting procedures and consider the hazards of other involved materials.

Special fire fighting procedures           Move containers from fire area if you can do so without risk.

Protection of fire-fighters              Wear suitable protective equipment.Use personal protective mask and fight fire from upwind, to avoid fumes upon combustion.

For non-emergency personnel

Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Wear appropriate protective equipment and clothing during clean-up. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. For personal protection, see section 8 of the SDS.

For emergency responders

Keep unnecessary personnel away. Use personal protection recommended in Section 8 of the SDS.

Environmental precautions

Avoid discharge into drains, water courses or onto the ground.

Methods and materials for containment and cleanup of chemical spills

Avoid the generation of dusts during clean-up. Collect dust using a vacuum cleaner equipped with HEPA filter. Prevent entry into waterways, sewer, basements or confined areas. Stop the flow of material, if this is without risk.

Large Spills: Wet down with water and dike for later disposal. Shovel the material into waste container. Following product recovery, flush area with water.

Small Spills: Sweep up or vacuum up spillage and collect in suitable container for disposal. For waste disposal, see section 13.

Prevention of secondary hazards          Not available.

Prevention of secondary hazards

Handling

Minimise dust generation and accumulation. Provide appropriate exhaust ventilation at places where dust is formed. Avoid prolonged exposure.

Practice good housekeeping.

Storage

Store in tightly closed container. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS). Keep dry and cool below 5°C for quality.

Carbon Black (CAS 1333-86-4)                               TWA         3 mg/m3      Inhalable fraction

Biological limit values          No biological exposure limits noted for the ingredient(s).

Recommended monitoring procedures             Follow standard monitoring procedures.

Control parameters          Follow standard monitoring procedures.

Engineering measures       Good general ventilation should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. If material is ground, cut, or used in any operation which may generate dusts, use appropriate local exhaust ventilation to keep exposures below the recommended exposure limits.

Personal protective equipment

Respiratory protection           Wear respirator with dust filter.

Hand protection              Wear protective gloves.

Eye protection           Wear safety glasses with side shields (or goggles).

Skin and body protection         Wear apron or protective clothing in case of contact.

Hygiene measures                         Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants.

Physical state        Solid.

Form             Tablet. Powder.

Colour    Black.

Odour          Epoxy.

Auto-ignition temperature           Not available. Decomposition temperature Not available.

Other data

Specific gravity                        1.8 - 2.2

Reactivity          The product is stable and non-reactive under normal conditions of use, storage and transport

Stability       Stable under recommended storage conditions.

Possibility of hazardous reactions    No dangerous reaction known under conditions of normal use.

Conditions to avoid           Contact with incompatible materials. Keep away from heat, moisture and sunlight for quality.

Incompatible materials          Strong oxidising agents. Strong acids, alkalies and oxidizing agents.

Hazardous decomposition products         Toxic gas.

LD50                                          Rat                                                                                      > 8000 mg/kg *

LD50                                          Rat                                                                                      > 22500 mg/kg * Silica(Amorphous) B (CAS 7631-86-9)

Acute

Oral

LD50                                          Rat                                                                                      >= 22500 mg/kg

Skin corrosion/irritation                Not available.

Serious eye damage/eye irritation           Not available.

Respiratory or skin sensitisation Respiratory sensitisation      Not available.

Carcinogenicity                                 Risk of cancer cannot be excluded with prolonged exposure.

Toxic to reproduction

Specific target organ toxicity following single exposure

Specific target organ toxicity following repeated exposure        Not available.

This product is not expected to cause reproductive or developmental effects          Not available.

Chronic effects                                  Prolonged inhalation may be harmful.

Prolonged exposure may cause chronic effects.

Ecotoxicity

The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. There are no data on the ecotoxicity of this product.

Persistence and degradability Bioaccumulation

No data is available on the degradability of any ingredients in the mixture. Not available.

Mobility in soil

No data available for this product.

Other hazardous effects                No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component.

Specific precautions

Keep cool below 5°C.

Keep containers tightly closed. And avoid leaks, spills or collapse of cargo to avoid damage to containers.

Occupational exposure limits for hazardous agents in the workplace (GBZ 2.1-2007)

Carbon Black (CAS 1333-86-4)

China SAWS GHS: Classification

Not applicable.

International regulations Stockholm Convention

Not applicable.

Rotterdam Convention

Not applicable.

Montreal Protocol

Not applicable.

Kyoto Protocol

Not applicable.

Basel Convention

Not applicable.

References

•ACGIH (2017)

•EPA: AQUIRE database

•NLM: Hazardous Substances Data Base HSDB® - Hazardous Substances Data Bank

•IARC (vol. 1~117)

•China. GBZ 2.1-2007: OELs. Occupational Exposure Limits for Hazardous Agents in the Workplace, Part 1, Chemical Hazardous Agents (March 2008)

•China. GB13690-2009: General rules for classification and hazard communication of chemicals.

•UN. Globally Harmonized System of Classification and Labelling of Chemicals (GHS) ST/SG/AC.10/30/Rev.4

•Japan. GHS Classifications of Regulated Chemicals (NITE)

•China. Guidance on the Compilation of Safety Data Sheet for Chemical Products (GB/T 17519-2013)

•China. Safety Data Sheet for Chemical Products - Content and Order of Sections (GB/T 16483-2008)

•China. GB 30000-2013: Rules for classification and labelling of chemicals.

•China. GB/T 32374-2015: Phrase and codification of chemical hazard statements.

Disclaimer

SUMITOMO BAKELITE CO., LTD. cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user’s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use