Product Name 化学品名称：PMTC Lead-free Solder ball Series 无铅锡球

Other Name 其他名称：Not applicable 不适用

Product Series 产品系列：Sn42Bi58 Sn42Bi57Ag1

The ball diameters are available on your request. 球径可依客户要求

Proposed use/Restrictions on the Use 建议用途及限制使用：

Electronics and semiconductor components, welding alloys 电子与半导体元件、焊接合金

Manufacturer / Supplier Information/ Address/ Telephone 制造者、输入者或供应者名称、地址及电话：

Manufacturer 制造者：Phichem Corporation 上海飞凯材料科技股份有限公司

Address 地 址：2999 Panjing Road, Baoshan, Shanghai, China, 201908 上海宝山区潘泾路2999号邮编:201908

Telephone 电 话：86-21-50551001 Email 电子邮件地址： tech@phichem.com.cn

Emergency Contact/Fax/Effective date 紧急连络电话、传真电话及生效日期：

Emergency Contact 紧急电话：86-21-50551001 Fax 传真：86-21-58993079

Effective date 生效日期：2020/12/9(Validity:3 years 有效期限：3 年)

Emergency overview 紧急情况概述：May cause damage to organs through prolonged or repeated exposure.长时间或反复接触可能造成器官损害。

Items Hazard Classification 化学品危害分类：Specific target organ toxicity (repeated exposure) ( Hazard category 2) 特异性靶器官毒性反复接触类别 2

Pictogram（s）

象形图

Hazard Classification

危险类型

Health Hazards.健康危害。

Signal Word

信号词

Warning.警告。

Hazard Statement

危险说明

May cause damage to organs through prolonged or repeated exposure. 长时间或反复接触可能造成器官损害。

Precautionary Statement

防范说明

Prevention ：Do not breathe dust/fume/gas/mist/vapours/spray. 预方措施：不要吸入粉尘/烟/气体/烟雾/蒸气/喷雾。

Response：Get medical advice/attention if you feel unwell.

应对措施：如觉不适，求医/就诊。

Storage：Store in a well-wentilated place. 存放：存放在通风良好的地方。

Disposal：Dispose of container in accordance with local/regional/international regulations. 处置：按照当地法规相关规定处置内装物和容器。

Taint Path

暴露途径

Inhalation、Skin Contact、Eye Contact、Ingestion。吸入、皮肤接触、眼睛接触、食入。

Environmental Hazards

环境危害

Not applicable. 不适用。

Explosion Risk

燃爆危险

Not applicable. 不适用。

Other Hazard 其他危害：No relevant document. 无相关资料可查。

Name 名称

Atomic number 原子量

Chemical

Code

化学式

Concentration or concentration ranges (% of contents)

浓度或浓度范围(成分百分比)

化学文摘杜登记号码

(CAS NO.)

Sn42Bi58

Sn42Bi57Ag1

Tin 锡

50

Sn

42±2

42±2

7440-31-5

Silver 银

47

Ag

--

1±0.2

7440-22-4

Bismuth 铋

83

Bi

Balance

Balance

7440-69-9

First Aid Methods for Different Exposure Pathways不同暴露途径之急救方法：

Inhalation

吸入

Remove to fresh air. If not breathing, have a trained individual administer oxygen. Get medical attention immediately. 将患者移至清新空气处，如果患者已停止呼吸，则施以人工呼吸并送急诊。

Skin Contact

Wash contaminated skin with non-abrasive soap and running water. Remove contaminated

皮肤接触

clothing. Get medical attention if skin irritation. 用适合的肥皂和清水清洗皮肤。除去污染的衣服。如果皮肤发炎, 马上就医。

Eye Contract

眼睛接触

Check for and remove any contact lenses, immediately flush with plenty of water for at least 15 minutes and get medical attention. 检查并移除任何隐形眼镜,马上用大清水冲洗至少15分钟,立即就医。

Ingestion

食入

Gargle. Induce vomiting by the medical staff instructions. 漱口。由医疗人员指示催吐。

The Most Important Symptoms and Hazardous Effect 最重要症状及危害效应：

Irritation and excessive exposure to hot steam cause pulmonary edema. 刺激感及过量吸入热蒸气会造成肺水肿。

Protection for First-aid Personnel 对急救人员之防护：

Wear gas masks, oxygen cylinders and protective clothing for First-aid personnel. 急救人员应配戴防毒面罩或氧气筒及防护衣。

Prompt to Doctor 对医师之提示：

Silver and inorganic compounds are neurotoxicants, they maybe bring peripheral nervous diseases. 银及其无机化合物为神经毒物，可能引起末梢经疾病。

Suitable Extinguishing

适用灭火剂

Carbon dioxide, extinguishing powder or water spray. 二氧化碳灭火剂，干粉或者水。

Special dangerous that may encounter while fire fighting

灭火时可能遭遇之特殊危害

No relevant document. 无相关资料可查。

Special fire fighting procedure

特殊灭火程序

Not suitable. 不适用。

Special safety equipment fire

消防人员之特殊防护设备

No relevant document. 无相关资料可查。

Hazardous properties

危险特性

Not suitable. 不适用。

Hazardous combustion products

有害燃烧产物

Not suitable. 不适用。

Personal precautions

个人应注意事项

Avoid inhalant soldering exhaust gas or dust. 避免吸入銲锡烟气或粉尘。

Environmental precautions

环境注意事项

Don't spread over the area. 勿使泄露区域广大。

Clean-up methods

清理方法

Pump the air or water spray. 抽气或冲洗。

Handling 处置

Keep 20 cm when soldering. The fumes produced during soldering should be extracted away from the breathing zone of the operators, use in a well ventilated area. When using, avoid contact or breathing. Do not eat, drink or smoke.

Thoroughly wash hands with soap and water after handling. Good industrial hygiene practices should be followed.

焊接时，保持20厘米距离。在焊接期间产生的烟雾应该被抽离操作者的呼吸区域，应在一个通风的地区里操作焊接。当焊接时，避免接触或者吸入。工作场所禁止吃东西，喝饮料及抽烟。操作后彻底洗净，保持良好工业卫生惯例。

Storage

储存

The guarantee of shelf life for solder ball is 1 year (12 months) when solder balls are stored under unopened bottles and pointed storage condition as following. 当锡球存放于未拆封的瓶子与以下的储藏环境时，锡球货架寿命的保证为一年(12 个月)。

Temperature / 温度 : 25 +/- 10 ℃

Humidity / 湿度 : < 65 %RH

Engineering Control工程控制：

Provide adequate mechanical exhaust. 提供足够的机械式排气装置。

Monitoring method 监控方法：Not applicable. 不适用。

Control Parameters 控制参数：

Allowable Concentration 容许浓度

Element 元素

TLV □ PEL □

Other

TWA

8小时平均容许浓度

STEL

短时间时平均容许浓度

Ceiling

最高容许浓度

Sn

2.0 mg/m3

4.0 mg/m3

---

Ag

0.1 mg/m3

0.03 mg/m3

---

Bi

0.5 mg/m3

1.8 mg/m3

---

Biological Indicators

生物指标

Not applicable. 不适用。

Personal Protection Equipment 个人防护设备：

Respiratory呼吸

Wear a NIOSH approved respirator to avoid over exposure 配戴批准的 NIOSH 的防毒面具以避免过度曝露。

Hands手部

Suitable gloves 防护手套。

Eyes 眼睛

For handling: wear safety glasses with side shields. For melting, wear goggles and face shields. Don’t wear contact lenses.

操作时︰配戴安全眼镜。熔化化合物时，配戴护目镜和面罩。不要戴隐形眼镜。

Skin and Body

Wear coveralls and protective gloves. Inspect gloves before using.

皮肤及身体

应穿戴工作衣及防护手套。在使用之前，检查手套。

Ambulance protection

救护人员防护

staff

Wear gas masks, oxygen cylinders and protective clothing. 配戴防毒面罩或氧气筒及防护衣。

Other precautions

其他注意事项

Forbid eating, drinking, smoking and make up in the workplace. 工作场所禁止吃东西，喝饮料、抽烟及化妆。

Hygiene practices 卫生措施：

Thoroughly wash exposed areas with soap and water before leaving work, eating, drinking and smoking. 工作后，吃东西、喝饮料或抽烟前应洗手。

Appearance 外观(物质状态、颜色)：

Silver-white metal 银白色金属

Odor 气味：Odorless 无气味

Olfactory Threshold 嗅觉阈值：Not applicable 不适用

Melting Point 熔点：217~229℃

pH 值：Not applicable 不适用

Flash Point 闪火点：Not applicable 不适用

Test Methods 测试方法(开杯或闭杯)：

Not applicable 不适用

Flammability 易燃性(固体、气体)：

Not applicable 不适用

Boiling/Boiling Point Range 沸点/沸点范围：

Not applicable 不适用

Resolve Temperature 分解温度：

Not applicable 不适用

Heat of Combustion 燃烧热(kJ/mol)：

Not applicable 不适用

Auto Ignition Temperature 自燃温度：

Not applicable 不适用

Explosion Limit 爆炸界限：

Not applicable 不适用

Vapor Pressure 蒸气压：Not applicable 不适用

Vapor Density 蒸气密度：Not applicable 不适用

Density 密度：7.4 g/cm3

Ignition Temperature 引燃温度：Not applicable 不适用

Solubility 溶解度：Insoluble in water 不溶于水

Evaporation Rate 挥发速率：Not applicable 不适用

Octanol / Water Partition Coefficient Values

辛醇/水分配系数：Not applicable 不适用

Chemical Stability 安定性：Stable under room temperature and pressure. 正常状况下安定。

Special circumstances of the hazard Reaction 特殊情况下可能之危害反应：Not applicable. 不适用。

Conditions to Avoid 应避免之状况：Contamination. Contact with air or water. 与空气或者水接触。

Materials to Avoid 应避免之物质：

Avoid oxidizing agents, acids, peroxides, moisture, chlorine, alkalies. 避免具氧化性之物质，酸，过氧化物，水分，氯，及硷。

Hazardous decomposition products 危害分解物：Not applicable. 不适用。

Route of Exposure 暴露途径：

Acute Toxicity 急毒性

LD50/经口

LD50/经皮24h

LD50/吸入

其它

NA

NA

NA

NA

Symptoms 症状：

Coughing, difficulty breathing, headache, nausea, vomiting. 咳嗽、呼吸困难、头痛、恶心、呕吐。

Chronic Toxicity or Long-term Toxicity 慢毒性或长期毒性：No relevant document. 无相关资料可查。

Induced sensitivity 致敏感性：NA

Irritation 刺激性：NA

Induced mutation 致突变性：NA

Teratogenicity 致畸性：NA

Reproductive toxicity 生殖毒性：NA

Specific target organ systemic toxicity 特异性靶器官系统毒性：No relevant document. 无相关资料可查。

Other 其它：NA

Eco-toxicity 生态毒性：

LC50(Fish 鱼类)：NA

EC50(Aquatic invertebrates 水生无脊椎动物)：NA biological Concentration factor 生物浓缩系数(BCF)：NA

Bioaccumulation 生物蓄积性：NA

Persistence and Degradability 持久性及降解性：NA

Biodegradable 生物降解性：NA

Non-biodegradable 非生物降解性：NA

The Mobility in soil 土壤中之流动性：NA

Other Adverse Effects 其他不良效应：NA

UN. No 联合国编号：NA

The United Nations shipping name 联合国运输名称：NA

Transportation hazard classification 运输危害分类：NA

Packing 包装类别：NA

Marine pollutant 海洋污染物(是/否)：NA

Special Shipping and Notes 特殊运送方法及注意事项：NA

Applicable Laws and Regulations适用法规：

1. Occupational safety and sanitation rules.职业安全卫生设施规则。
2. Hazards and hazardous materials rules of Liberal Studies. 危险物及有害物通规则。
3. Labor working industry in ambient air concentrations of hazardous materials to allow the standard. 工作业环境空气中有害物容许浓标准。
4. Road Traffic Safety Rules. 道交通安全规则。
5. Industrial Waste Management Methods for storage clearance office and Facilities Standards. 事业废弃物贮存清除处方法及设施标准。

List of Chemicals Management in China 中国化学品管理名录：

1. Catalogue of Hazardous Chemicals （2015） 危险化学品目录（2015 年版） 未列入
2. Catalogue of Key Environmental Management Dangerous Chemicals 未列入重点环境管理危险化学品目录
3. China's Strict List of Toxic Chemicals 中国严格限制的有毒化学品名录 未列入
4. Catalogue of Narcotic Drugs and Psychotropic Substances（2013） 未列入麻醉药品和精神药品品种目录（2013 版）
5. List of Hazardous Chemicals under Special Supervision （batches 1 and 2） 未列入重点监管的危险化学品名录（第 1 和第 2 批）
6. List of Controlled Ozone Layer Depleting Substances in China's Imports and Exports （batches 未列入

1 to 6） 中国进出口受控消耗臭氧层物质名录（第 1 到 6 批）

7. List of Inflammable and Explosive Dangerous Chemicals （2017） 未列入制爆危险化学品名录（2017 年版）
8. List of High Toxic 高毒物品目录 未列入

References

参考文献

1.AIR PRODUCTS MSDS、INTERN TIONAL MARITIME DANGEROUS GOODS

CODE

2.MSDS Library, CCINFO, 9 9 -2, 2006-1

3.RTECS Library, TOMES PLUS, Vol.68, 2006

4.HSDS Library, TOMES PLUS, Vol.68, 2006

5. GB/T16483-2008 ，化学品安全技术说明书内容和项目顺序

6. GB/T 17519-2013，化学品安全技术说明书编写指南
7. GB 30000，化学品分类和标签规范

Tabulated Company

制表者单位

Name 名称：PhiChem Corporation.上海飞凯材料科技股份有限公司

Address 地址：2999 Panjing Road, Baoshan, Shanghai, China, 201908 上海宝山区潘泾路2999号邮编:201908

Telephone 电话：86-21-50551001

Fax传真：86-21-58993079

Prepared by

制表者

Position 职称：PSRA Engineer

Name (Signature)姓名(签章)：Wang Linjing

Tabulated Date

制表日期

2018/09/10

Rev. / Edit

Description

版次/修改说明

2022/8/11

B18

定期 review，更新改版、发行、生效日期。

Other message

其他信息

NA

Disclaimer

免责声明

The data contained herein are furnished for information only and are believed to be reliable. However, Shanghai PhiChem Material Corporation Limited (“PhiChem”) does not assume responsibility for any results obtained by persons over whose methods PhiChem has no control. It is the user’s responsibility to determine the suitability of PhiChem’s product or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any hazards that may be involved in the handling and use of any PhiChem’s products. In light of the foregoing, PhiChem specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of PhiChem’s products. PhiChem further disclaims any liability for consequential or incidental damages of any kind, including lost profits.

本说明书是基于我们现在的知识水平所得，它不是产品特性的保证书。安全技术说明书的使用者应根据使用目的，对相关信息的合理性做出判断。我们对该产品操作、存储、使用或处置等环节产生的任何损害，不承担任何责任。